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Fe-Mn-Si-Cr-Ni记忆合金形变组织的TEM研究

戎利建 , 平德海 , 李依依 , 师昌绪

金属学报

本文利用X射线衍射及透射电镜分析研究了元素Cr,Ni对Fe-Mn-Si合金c/a值及形变诱发ε马氏体显微组织的影响.结果表明:添加Cr,Ni后.合金的c/a值由1.620提高至1.656,其结果使合金中的fcc形变孪晶易形成:通过在孪晶内形成ε马氏体,可避免不同取向马氏体之间的穿越过程,从而有利于合金的记忆效应.

关键词: 记忆合金 , ε martensite , deformation twin , stress concentration

STUDY ON THE MAGNETISM AND PHASE TRANSFORMATION IN Fe-Mn-Si-C SHAPE MEMORY ALLOYS

Z.X Qinand Y.S. Zhang(Department of Materials Science and Engineering , Dalian Railway Institute , Dalian 116028 , China)

金属学报(英文版)

The hyperfine interactions of two shape memory alloys have been studied by Mossbauer effect measurement at various temperatures. The Mossbauer spectra exhibit a mag-netic change from antiferro magnetic state to paramagnetic state when the temperuture rises. The Fe-Mn-Si alloys have a small hyperfine field and silicon element increases the hyperfine field and magnetic susceptibility. Thermo-induced γ→ ε trunsforma-tions are suppressed by Neel transition and by increasing carbon content, whereas stress induced γ→ ε transformation occurs in both alloys. Antiferromagnetic spin order can suppress thermo-induced γ→εtransformations efficiently, but cannot sup-press stress induced γ → ε transformation.

关键词: phase transformation , null , null , null

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